Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(ii) complexes
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چکیده
منابع مشابه
Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes.
The reaction of a methanolic solution containing the bi-compartmental phenolic ligand 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-chlorophenol (L(Cl)-OH) with MCl2·nH2O in the presence of NH4PF6 or NaClO4 afforded the dinuclear bridged-phenoxido dichlorido-metal(ii) complexes [Co2(μ-L(Cl)O)(H2O)2Cl2][Co2(μ-L(Cl)O)(MeOH)2Cl2](PF6)2 (), [Ni2(μ-L(Cl)O)(MeOH)2Cl2]PF6 (), [Ni2(μ-L(Cl)O)(MeOH)(H2O)Cl2...
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Two chiral dinuclear cyanide/isocyanide-bridged complexes (R)-[Cp(dppe)Fe-CN-Fe(dppp)Cp]PF6 (1[PF6]) and (R)-[Cp(dppe)Fe-NC-Fe(dppp)Cp]PF6 (2[PF6]), and their mono-oxidation products (R)-[Cp(dppe)Fe(II)-CN-Fe(III)(dppp)Cp] [PF6]2 (1[PF6]2) and (R)-[Cp(dppe)Fe(III)-NC-Fe(II)(dppp)Cp][PF6]2 (2[PF6]2) were synthesized and fully characterized. The electronic spectra of both the mixed-valence comple...
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The synthesis, spectroscopic and magnetic characterization of a series of new alkoxo-bridged binuclear copper (II) compounds are described. All complexes have the general formula [Cu (m-OR)(L)2]2(ClO4)2 · x H2O, in which m-OR = CH3O-, C2H5O- or C3H7O-<e...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2015
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c4dt03508a